Block (periodic table)

A block of the periodic table of elements is a set of adjacent groups. The term appears to have been first used by Charles Janet. The respective highest-energy electrons in each element in a block belong to the same atomic orbital type. Each block is named after its characteristic orbital; thus, the blocks are:

The block names (s, p, d, f and g) are derived from the spectroscopic notation for the associated atomic orbitals: sharp, principal, diffuse and fundamental, and then g which follows f in the alphabet.

The following is the order for filling the "subshell" orbitals, according to the Aufbau principle, which also gives the linear order of the "blocks" (as atomic number increases) in the periodic table:

For discussion of the nature of why the energies of the blocks naturally appear in this order in complex atoms, see atomic orbital and electron configuration.

The "periodic" nature of the filling of orbitals, as well as emergence of the s, p, d and f "blocks" is more obvious, if this order of filling is given in matrix form, with increasing principal quantum numbers starting the new rows ("periods") in the matrix. Then, each subshell (composed of the first two quantum numbers) is repeated as many times as required for each pair of electrons it may contain. The result is a compressed periodic table, with each entry representing two successive elements:

Block (rural Australia)

Block is an Australian term for a small agricultural landholding. Block settlement has been used by Governments to encourage decentralization and during financial depressions to give families of unemployed workers an opportunity (frequently illusory) to become primary producers. It may also refer to a lifestyle choice or "hobby farm" for those with an independent source of income.

In parts of Australia, parcels of land of around 6 to 20 acres (2 to 8 ha) were allocated by Government to working-class men at nominal rent during the depression of the 1890s with the object of giving them work and, potentially, a source of income. Some eventually prospered, but those on marginal land were doomed to failure. Proponents of the "block system" included George Witherage Cotton. Holders of such allotments were referred to as "blockers" or "blockies".

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Block (data storage)

In computing (specifically data transmission and data storage), a block, sometimes called a physical record, is a sequence of bytes or bits, usually containing some whole number of records, having a maximum length, a block size. Data thus structured are said to be blocked. The process of putting data into blocks is called blocking, while deblocking is the process of extracting data from blocks. Blocked data is normally stored in a data buffer and read or written a whole block at a time. Blocking reduces the overhead and speeds up the handling of the data-stream. For some devices such as magnetic tape and CKD disk devices blocking reduces the amount of external storage required for the data. Blocking is almost universally employed when storing data to 9-track magnetic tape, to NAND flash memory, and to rotating media such as floppy disks, hard disks, and optical discs.

Most file systems are based on a block device, which is a level of abstraction for the hardware responsible for storing and retrieving specified blocks of data, though the block size in file systems may be a multiple of the physical block size. This leads to space inefficiency due to internal fragmentation, since file lengths are often not integer multiples of block size, and thus the last block of a file may remain partially empty. This will create slack space, which averages half a block per file. Some newer file systems attempt to solve this through techniques called block suballocation and tail merging.

Grand

Grand may refer to:

Music

People

Places

Transport

Other uses

Grandparent

Grandparents are the parents of a person's father or mother – paternal or maternal. Every sexually-reproducing creature who is not a genetic chimera has a maximum of four genetic grandparents, eight genetic great-grandparents, sixteen genetic great-great-grandparents, etc., although the numbers will be lower in cases of pedigree collapse. In the history of modern humanity, around 30,000 years ago, the number of modern humans who lived to be grandparents increased exponentially. It is not known for certain what spurred this increase in longevity, but it is generally believed that a key consequence of three generations being alive together was the preservation of information which could otherwise have been lost; an example of this important information might have been where to find water in times of drought.

In cases where parents are unwilling or unable to provide adequate care for their children (e.g., death of the parents), grandparents often take on the role of primary caregivers. Even when this is not the case, and particularly in traditional cultures, grandparents often have a direct and clear role in relation to the raising, care and nurture of children. Grandparents are second-degree relatives and share 25% genetic overlap.

2345 Grand

2345 Grand (formerly the IBM Plaza, IBM Building and Mutual Benefit Life Insurance Company Building) is a skyscraper in Kansas City Missouri. It is listed on many sites as being the work of Mies van der Rohe, however, he died in 1969 before the 1977 opening. The work was done by Fujikawa Conterato Lohan & Associates. The International style building is a smaller version of the IBM Plaza in Chicago that is also attributed to Mies.

The building was originally built to be both the western headquarters of now defunct Mutual Benefit Life Insurance Company and an IBM office. At the time, it was called both the Mutual Benefit Building and the IBM Building.

It was acquired by the Shorenstein Company, who sold the building for $49.5 million in 2004 to Hines Interests LP and GE Real Estate. They in turn sold the building for $75 million in December 2007 to Franklin Street Properties Corp.

The current principal tenant in the building is the law firm of Lathrop & Gage, which occupies nine floors of the building. It also houses Missouri's Federal Immigration Court.